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Updated: May 14, 2025

Accessing Valuable Ligand Supports for Transition Metals: A Modified, Intermediate Scale Preparation of 1,2,3,4,5-Pentamethylcyclopentadiene
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Accessing Valuable Ligand Supports for Transition Metals: A Modified, Intermediate Scale Preparation of 1,2,3,4,5-Pentamethylcyclopentadiene

Published on: March 20, 2017

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ピリジン ((ダイミン) クロミウム η,1η3 - アルケーン-ダイエンの前触媒としての金属サイクル [2 + 2] サイクル添加

Hanna H Cramer1, Matthew V Pecoraro1, Paul J Chirik1

  • 1Department of Chemistry, Princeton University, Princeton, New Jersey 08544, United States.

Journal of the American Chemical Society
|April 11, 2025
PubMed
まとめ

この研究は,サイクロアディション反応を触媒するクロミウム複合体を詳細に示しています. 可視光は,ブタディーネとエチレンの選択的な [2 + 2] サイクロアディションを可能にし,ビニルサイクロブタン製品を形成します.

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