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Updated: May 11, 2025

Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-phosphinetriyltripiperidine]}palladium Under Mild Reaction Conditions
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Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-phosphinetriyltripiperidine]}palladium Under Mild Reaction Conditions

Published on: March 20, 2014

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テート・ブタノールを用いたメチラティブ・クロスカップリングのためのシナギスティックLMCTとNi触媒:選択的結合ホモリシスによるラジカル経路の調節

Lingfei Duan1, Yunzhi Lin1, Qing An1

  • 1State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, University of Chinese Academy of Sciences, Shanghai 200032, China.

Journal of the American Chemical Society
|April 19, 2025
PubMed
まとめ

この研究では,リガンドから金属への電荷移転 (LMCT) とニッケル触媒を用いた新しい光触媒法が導入され,効率的なC-CH3結合形成のためにテルトブタノールからメチルラジカルを生成します. このアプローチはメチル化反応に より環境にやさしい代替手段を提供する.

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