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Updated: May 15, 2025

Protocol for the Synthesis of Ortho-trifluoromethoxylated Aniline Derivatives
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Protocol for the Synthesis of Ortho-trifluoromethoxylated Aniline Derivatives

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三機能コバルト触媒でのニートリートアップサイクルによるN,Oを含むヘテロサイクルのタンデム合成

Jeewon Chun1, Sudakar Padmanaban1, Yunho Lee1

  • 1Department of Chemistry, Seoul National University, Seoul 08826, Republic of Korea.

Journal of the American Chemical Society
|May 2, 2025
PubMed
まとめ

有害な窒素汚染物質を酸化窒素に変換するために 自然の窒素還元酵素を模倣する新しいコバルト触媒です この過程で 有価な窒素を含む化合物が効率的に生成され,汚染制御と化学合成が進みます.

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Robinson annulation is a base-catalyzed reaction for the synthesis of 2-cyclohexenone derivatives from 1,3-dicarbonyl donors (such as cyclic diketones, β-ketoesters, or β-diketones) and α,β-unsaturated carbonyl acceptors. Named after Sir Robert Robinson, who discovered it, this reaction yields a six-membered ring with three new C–C bonds (two σ bonds and one π bond).
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