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Updated: Apr 7, 2026

Preparation of a Corannulene-functionalized Hexahelicene by CopperI-catalyzed Alkyne-azide Cycloaddition of Nonplanar Polyaromatic Units
09:35

Preparation of a Corannulene-functionalized Hexahelicene by CopperI-catalyzed Alkyne-azide Cycloaddition of Nonplanar Polyaromatic Units

Published on: September 18, 2016

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テルペンアルカロイド天然製品の総合成のための触媒非対称内分子 [4 + 1]サイクル添加

Wen Xiu1, Calvin D Huffman1, William A Swann1

  • 1Department of Chemistry, Purdue University, West Lafayette 47907, Indiana, United States.

Journal of the American Chemical Society
|May 12, 2025
PubMed
まとめ

新しいニッケル触媒反応により,非対称な分子内 [4 + 1] - サイクロアディションが可能になり,複雑な [4.3.0] - アザビサイクルのフレームワークが生成されます. この方法は,様々な多循環性天然物質を合成するのに有用です.

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