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Updated: May 15, 2025

Solid-phase Synthesis of [4.4] Spirocyclic Oximes
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パターン認識とオレフィントランスポーゼーションにより可能となる (-) - イリシモニンAの総合成

Bo Xu1, Ziyao Zhang1, Mingji Dai1,2

  • 1Department of Chemistry, Emory University, Atlanta, Georgia 30322, United States.

Journal of the American Chemical Society
|May 13, 2025
PubMed
まとめ

この研究は,複合性セスクイテルペンである (-) - イリシモニンAの最初の非対称合成を示しています. 16段階の合成により 独特でストレートなペンタサイクルの構造とステレオセンターが 効率的に作られます

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