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Updated: Jun 12, 2025

Reconstitution of Basic Mitotic Spindles in Spherical Emulsion Droplets
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Reconstitution of Basic Mitotic Spindles in Spherical Emulsion Droplets

Published on: August 13, 2016

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ストキャスティック核化によるラセミック溶液からのホモキラルサスペンションの自発的出現

Leif-Thore Deck1,2, Mercedeh Sadat Hosseinalipour1, Marco Mazzotti1

  • 1Institute of Energy and Process Engineering, ETH Zurich, Zurich 8092, Switzerland.

Journal of the American Chemical Society
|May 25, 2025
PubMed
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Racemic Mixtures and the Resolution of Enantiomers

A racemic mixture, or racemate, is an equimolar mixture of enantiomers of a molecule that can be separated using their unique interaction with chiral molecules or media. Racemic mixtures are denoted by the (±)- prefix. This ‘optical rotation descriptor’ applies to the whole solution of a racemic mixture rather than a specific stereoisomer. Enantiomers typically have the same physical and chemical properties. Hence, they are not easily separable. However, enantiomers can exhibit...
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This lesson provides an in-depth discussion of the stereochemical outcomes in an SN1 reaction.
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Stereochemistry is the study of the different spatial arrangements of atoms in a given molecule. The stereochemistry of radical halogenations can be understood from three different situations:
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The concept of prochirality leads to the nomenclature of the individual faces of a molecule and plays a crucial role in the enantioselective reaction. It is a concept where two or more achiral molecules react to produce chiral products. A typical process is the reaction of an achiral ketone to generate a chiral alcohol. Here, the achiral reactant reacts with an achiral reducing agent, sodium borohydride, to generate an equimolar mixture of the chiral enantiomers of the product. For example, an...
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