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Updated: Jun 16, 2025

Isolating Free Carbenes, their Mixed Dimers and Organic Radicals
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Isolating Free Carbenes, their Mixed Dimers and Organic Radicals

Published on: April 19, 2019

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平面性は明らかではない:構造的に制約され,2倍に減少したアリルボランのフルオルベンゼンに対する閉殻対開殻反応性

Christoph D Buch1, Alexander Virovets1, Eugenia Peresypkina1

  • 1Institut für Anorganische und Analytische Chemie, Goethe-Universität Frankfurt, Max-von-Laue-Straße 7, D-60438 Frankfurt am Main, Germany.

Journal of the American Chemical Society
|May 29, 2025
PubMed
まとめ

2つの電子によって活性化された構造的に制限された9,10-ジヒドロ-9,10-ジボラアントラセン (DBAs) は,フッ素ベンゼンの小分子活性化を可能にします. この研究は,フッ素化度および反定定性に応じて,核愛体または還元剤として作用するDBAを明らかにしています.

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