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Updated: Jun 12, 2025

A Microwave-Assisted Direct Heteroarylation of Ketones Using Transition Metal Catalysis
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A Microwave-Assisted Direct Heteroarylation of Ketones Using Transition Metal Catalysis

Published on: February 16, 2020

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Pd ((0) によるアリルハリド活性化のステリック誘導加速: 2電子酸化添加の根本的な代替方法

Daniel Hupperich1, Jaime Ponce-de-León1, Ignacio Funes-Ardoiz1

  • 1Institute of Organic Chemistry, RWTH Aachen University, Landoltweg 1, 52074 Aachen, Germany.

Journal of the American Chemical Society
|May 29, 2025
PubMed
まとめ

ステリック阻害はパラジウム触媒によるクロスカップリング反応を加速する. この研究は,先の2電子の仮定に異議を唱える,ステリックに要求される環境における1電子ハロゲン抽象機構を明らかにする.

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