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Updated: Jun 16, 2025

Exploring the Radical Nature of a Carbon Surface by Electron Paramagnetic Resonance and a Calibrated Gas Flow
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Exploring the Radical Nature of a Carbon Surface by Electron Paramagnetic Resonance and a Calibrated Gas Flow

Published on: April 24, 2014

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ニッケル媒介のラジカルキャプチャー: 協調した内層メカニズムの証拠

Ethan H Spielvogel1, Jonathan Yuan1, Norah M Hoffmann1

  • 1Department of Chemistry, New York University, 100 Washington Square East, New York, New York 10003, United States.

Journal of the American Chemical Society
|May 30, 2025
PubMed
まとめ

この研究では,ニッケル触媒は,炭素-炭素結合の形成に段階的にではなく,協調した経路を使用することを明らかにしています. レドックス活性リガンドは,ニッケル触媒によるクロスカップリング反応におけるこの根幹捕獲メカニズムに不可欠である.

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