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Updated: Sep 19, 2025

Measurement of the Potential Rates of Dissimilatory Nitrate Reduction to Ammonium Based on 14NH4+/15NH4+ Analyses via Sequential Conversion to N2O
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Measurement of the Potential Rates of Dissimilatory Nitrate Reduction to Ammonium Based on 14NH4+/15NH4+ Analyses via Sequential Conversion to N2O

Published on: October 7, 2020

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電気化学的窒素還元の活性を解明する: 動的ゲートキーパーとしての高値アニオン中間物質

Sheng-Jie Qian1, Hao Cao1, Xin-Mao Lv1

  • 1State Key Laboratory of Quantum Functional Materials and Department of Chemistry, Southern University of Science and Technology, Shenzhen, Guangdong 518055, China.

Journal of the American Chemical Society
|June 3, 2025
PubMed
まとめ

研究者は,高値の中間物質を特定することによって,電気化学的窒素還元における高過剰ポテンシャルパラドックスを解決しました. この発見は効率的なアンモニアの 電気合成と触媒設計の鍵です

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All meta-directing substituents are deactivating groups. These substituents withdraw electrons from the aromatic ring, making the ring less reactive toward electrophilic substitution. For example, the nitration of nitrobenzene is 100,000 times slower than that of benzene because of the deactivating effect of the nitro group. The first step in an electrophilic aromatic substitution is the addition of an electrophile to form a resonance-stabilized carbocation. The energy diagrams for...
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