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Updated: Sep 19, 2025

Facile Preparation of 2Z,4E-Dienamides by the Olefination of Electron-deficient Alkenes with Allyl Acetate
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Facile Preparation of 2Z,4E-Dienamides by the Olefination of Electron-deficient Alkenes with Allyl Acetate

Published on: June 21, 2017

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非対称バイメタリック触媒によるアルケニルZ/E相互同化

Guanlin Li1, Ziyun Lai1, En Zheng2

  • 1Shanghai Key Laboratory for Molecular Engineering of Chiral Drugs, State Key Laboratory of Synergistic Chem-Bio Synthesis, Frontiers Science Center for Transformative Molecules, School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, 800 Dongchuan Road, Shanghai 200240, China.

Journal of the American Chemical Society
|June 5, 2025
PubMed
まとめ

この研究では,キラルアミノ酸誘導体のステレオ定義された合成を可能にするオレフィンの双方向Z/E同化のための新しいPd/Cu触媒法が導入されています. このスケーラブルなプロセスは,価値あるアルケニル化合物の高収量とエナチオ選択性を達成します.

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