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Updated: Sep 19, 2025

Synthesis of Antiviral Tetrahydrocarbazole Derivatives by Photochemical and Acid-catalyzed C-H Functionalization via Intermediate Peroxides CHIPS
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イリジウムポリピリジル炭酸塩は,活性化されていないC-H結合の機能化のためのPCET触媒である

Diego A Granados1, Y Emily Du1, Shiloh J Andersson1

  • 1Department of Chemistry, Princeton University, Princeton, New Jersey 08544, United States.

Journal of the American Chemical Society
|June 10, 2025
PubMed
まとめ

新しいイリジウム触媒は,可視光を用いて非反応性C−H結合を活性化します. これらの触媒は,ペンデントカルボキシラートを含み,刺激状態の陽子結合電子移転を通じて効率的なC-Hアルキル化を可能にし,新しい合成方法への道を開く.

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