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Updated: Sep 19, 2025

Facile Preparation of 2Z,4E-Dienamides by the Olefination of Electron-deficient Alkenes with Allyl Acetate
06:46

Facile Preparation of 2Z,4E-Dienamides by the Olefination of Electron-deficient Alkenes with Allyl Acetate

Published on: June 21, 2017

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イリジウム触媒Z-選択的非対称性アリル置換反応によるZ/E運動解像度

Yi-Ming Hou1, Ru Jiang1, Jiandong Liu1

  • 1New Cornerstone Science Laboratory, State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Lu, Shanghai 200032, China.

Journal of the American Chemical Society
|June 10, 2025
PubMed
まとめ

この研究では,Z/E混合物からキラルZ-オレフィンを作るためのIr-触媒化された方法が紹介されています. 運動解像度と光誘発性異体化を利用し,Z-オレフィン合成に挑戦するために高収量とエナチオ選択性を達成します.

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