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Updated: Sep 18, 2025

Design, Synthesis, and Photochemical Properties of Clickable Caged Compounds
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Design, Synthesis, and Photochemical Properties of Clickable Caged Compounds

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機能化されたオリゴフェニレンケージの共性テンプレート誘導合成

Kosuke Ono1, Fumito Sasamori1, Hatsune Izawa1

  • 1Department of Chemistry, School of Science, Institute of Science Tokyo, Ookayama, Meguro-ku, Tokyo 152-8551, Japan.

Journal of the American Chemical Society
|June 25, 2025
PubMed
まとめ

オリゴフェニレンケージを 合成するコヴァレンント・テンプレート・ガイド・メソッドを開発しました このアプローチは,テンプレートのない方法と比較してケージ形成の収率を大幅に改善し,効率的な分子封じ込みを可能にします.

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Selection Rules: Thermal Activation
Conjugated systems containing an even number of π-electron pairs undergo a conrotatory ring closure. For example, thermal electrocyclization of (2E,4E)-2,4-hexadiene, a conjugated diene containing two π-electron pairs, gives trans-3,4-dimethylcyclobutene.
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