ニッケルメタラフォトレドックス触媒における酸化添加過渡状態の探査 内分子C動態同位体効果を用いて

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Updated: Sep 17, 2025

Synthesis and Performance Characterizations of Transition Metal Single Atom Catalyst for Electrochemical CO2 Reduction
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Synthesis and Performance Characterizations of Transition Metal Single Atom Catalyst for Electrochemical CO2 Reduction

Published on: April 10, 2018

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Chetan Joshi1, Julia R Dorsheimer2, Victor O Nyagilo1

  • 1Department of Chemistry, Binghamton University, Binghamton, New York 13902, United States.

Journal of the American Chemical Society
|July 1, 2025
PubMed
まとめ

ニッケル・フォトレドックス触媒は軽度のC−CとC−X結合を形成する. 内分子C運動同位体効果 (KIEs) は,酸化添加におけるニッケル種を明らかにし,C2−C3クロスカップリングおよびアミンアリレーション反応の触媒サイクルを明らかにする.

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