パラジウムにおける異動的運動/熱力学的選択性 ((II) 媒介によるC-H活性化による5つまたは6つ構成のパラディウムサイクル形成

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Updated: Sep 15, 2025

Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-phosphinetriyltripiperidine]}palladium Under Mild Reaction Conditions
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Published on: March 20, 2014

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Philip S Zhou1, Kyana M Sanders1, Ilia A Guzei1

  • 1Department of Chemistry, University of Wisconsin─Madison, Madison, Wisconsin 53706, United States.

Journal of the American Chemical Society
|July 15, 2025
PubMed
まとめ

パラジウム触媒は通常6つの環を形成しますが,この研究では5つの環がより安定していることが判明しました. 柔軟なリガンドを使用すると,パラジウム触媒によるC-H活性化が促進され,反応効率が向上します.

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