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Updated: Sep 8, 2025

Preparation of a Corannulene-functionalized Hexahelicene by CopperI-catalyzed Alkyne-azide Cycloaddition of Nonplanar Polyaromatic Units
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Preparation of a Corannulene-functionalized Hexahelicene by CopperI-catalyzed Alkyne-azide Cycloaddition of Nonplanar Polyaromatic Units

Published on: September 18, 2016

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フラーレンの封じ込みを介してヘリカル共性有機フレームワークにおけるキラリティ誘発のスピン選択性の増幅

Xiaofeng Zhang1, Shiguo Fu1, Lei Jia1

  • 1State Key Laboratory of Synergistic Chem-Bio Synthesis, School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai 200240, China.

Journal of the American Chemical Society
|July 16, 2025
PubMed
まとめ

スピントロニクスにおけるキラル性誘発スピン選択性 (CISS) は,キラルフレームワークにフルレンをカプセル化することによって強化される. このホスト・ゲスト戦略は スピンの偏分を大きく高め 先進的な電子機器への道を切り開きます

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The concept of prochirality leads to the nomenclature of the individual faces of a molecule and plays a crucial role in the enantioselective reaction. It is a concept where two or more achiral molecules react to produce chiral products. A typical process is the reaction of an achiral ketone to generate a chiral alcohol. Here, the achiral reactant reacts with an achiral reducing agent, sodium borohydride, to generate an equimolar mixture of the chiral enantiomers of the product. For example, an...
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The chair form is the most stable and derives its name from its resemblance to the “easy chair.” In the chair conformation, two carbon atoms are arranged out-of-plane — one above and one below, minimizing the torsional strain. In the chair form, the bond angle is very close to the ideal...
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