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Updated: Sep 15, 2025

Preparation and Reactivity of a Triphosphenium Bromide Salt: A Convenient and Stable Source of PhosphorusI
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Preparation and Reactivity of a Triphosphenium Bromide Salt: A Convenient and Stable Source of PhosphorusI

Published on: November 22, 2016

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キラルサポート電解質によるフォスフィンの動的運動解像度

Kaining Mao1, Chenfei Liu1, Yi Wang1

  • 1Department of Chemistry and Chemical Biology, Cornell University, Ithaca, NY, USA.

Nature
|July 16, 2025
PubMed
まとめ

研究者らは,キラル・フォスファート塩を補助電解質として用いて,エナチオプア・フォスフィン酸化物を生成する新しい方法を開発した. これは持続可能な有機合成と 非対称な電気化学を推進します

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Chirality is most prevalent in carbon-based tetrahedral compounds, but this important facet of molecular symmetry extends to sp3-hybridized nitrogen, phosphorus and sulfur centers, including trivalent molecules with lone pairs. Here, the lone pair behaves as a functional group in addition to the other three substituents to form an analogous tetrahedral center that can be chiral.
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