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Updated: Sep 14, 2025

Versatile CO2 Transformations into Complex Products: A One-pot Two-step Strategy
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Si = Si ダブルボンドへの可逆的なCO挿入は,後続的なCO2添加を通じてディシラビスラクトン形成を可能にします

Fiona J Kiefer1, Arseni Kostenko1, Richard Holzner1

  • 1TUM School of Natural Sciences, Department of Chemistry, Institute of Silicon Chemistry and Catalysis Research Center, Technische Universität München, Lichtenbergstraße 4, Garching bei München 85748, Germany.

Journal of the American Chemical Society
|July 21, 2025
PubMed
まとめ

炭素一酸化物は,シリコン-シリコンの二重結合に挿入し,新しいディシラアルレン酸化物を形成する. この反応はイミノ置換化合物では逆転し,新しい合成経路を提供する.

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