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関連する概念動画

Third Law of Thermodynamics02:38

Third Law of Thermodynamics

19.5K
A pure, perfectly crystalline solid possessing no kinetic energy (that is, at a temperature of absolute zero, 0 K) may be described by a single microstate, as its purity, perfect crystallinity,and complete lack of motion means there is but one possible location for each identical atom or molecule comprising the crystal (W = 1). According to the Boltzmann equation, the entropy of this system is zero.
19.5K
Second Law of Thermodynamics02:49

Second Law of Thermodynamics

24.3K
In the quest to identify a property that may reliably predict the spontaneity of a process, a promising candidate has been identified: entropy. Processes that involve an increase in entropy of the system (ΔS > 0) are very often spontaneous; however, examples to the contrary are plentiful. By expanding consideration of entropy changes to include the surroundings, a significant conclusion regarding the relation between this property and spontaneity may be reached. In thermodynamic...
24.3K
Entropy and the Second Law of Thermodynamics01:20

Entropy and the Second Law of Thermodynamics

3.2K
The second law of thermodynamics can be stated quantitatively using the concept of entropy. Entropy is the measure of disorder of the system.
The relation  between entropy and disorder can be illustrated with the example of the phase change of ice to water. In ice, the molecules are located at specific sites giving a solid state, whereas, in a liquid form, these molecules are much freer to move. The molecular arrangement has therefore become more randomized. Although the change in average...
3.2K
Heating and Cooling Curves02:44

Heating and Cooling Curves

24.0K
When a substance—isolated from its environment—is subjected to heat changes, corresponding changes in temperature and phase of the substance is observed; this is graphically represented by heating and cooling curves.
For instance, the addition of heat raises the temperature of a solid; the amount of heat absorbed depends on the heat capacity of the solid (q = mcsolidΔT). According to thermochemistry, the relation between the amount of heat absorbed or released by a substance, q, and its...
24.0K
Diversity of Archaea IV01:29

Diversity of Archaea IV

109
Hyperthermophilic archaea are a group of extremophiles thriving at temperatures above 80°C, often in hydrothermal vents and volcanic soils where conditions surpass the boiling point of water. At such temperatures, proteins, membranes, and DNA in most organisms degrade, but hyperthermophiles have evolved remarkable adaptations to maintain stability and function.Unique Cellular FeaturesHyperthermophilic membranes are composed of a monolayer of biphytanyl tetraether lipids, which resist...
109
Phase Transitions: Melting and Freezing02:39

Phase Transitions: Melting and Freezing

13.2K
Heating a crystalline solid increases the average energy of its atoms, molecules, or ions, and the solid gets hotter. At some point, the added energy becomes large enough to partially overcome the forces holding the molecules or ions of the solid in their fixed positions, and the solid begins the process of transitioning to the liquid state or melting. At this point, the temperature of the solid stops rising, despite the continual input of heat, and it remains constant until all of the solid is...
13.2K

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関連する実験動画

Updated: Sep 14, 2025

Laser-heating and Radiance Spectrometry for the Study of Nuclear Materials in Conditions Simulating a Nuclear Power Plant Accident
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Laser-heating and Radiance Spectrometry for the Study of Nuclear Materials in Conditions Simulating a Nuclear Power Plant Accident

Published on: December 14, 2017

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予測されるエントロピーの破滅的限界を超えた高温の金

Thomas G White1, Travis D Griffin2, Daniel Haden2

  • 1Department of Physics, University of Nevada, Reno, NV, USA. tgwhite@unr.edu.

Nature
|July 23, 2025
PubMed
まとめ

研究者は理論的な理論に挑戦し

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Microscopic Visualization of Porous Nanographenes Synthesized through a Combination of Solution and On-Surface Chemistry
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Microscopic Visualization of Porous Nanographenes Synthesized through a Combination of Solution and On-Surface Chemistry

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Synthesis and Catalytic Performance of Gold Intercalated in the Walls of Mesoporous Silica
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Synthesis and Catalytic Performance of Gold Intercalated in the Walls of Mesoporous Silica

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関連する実験動画

Last Updated: Sep 14, 2025

Laser-heating and Radiance Spectrometry for the Study of Nuclear Materials in Conditions Simulating a Nuclear Power Plant Accident
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Synthesis and Catalytic Performance of Gold Intercalated in the Walls of Mesoporous Silica
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科学分野:

  • 材料科学
  • 熱力学について
  • 固体物理学

背景:

  • 固体の安定性の上限を予測している.
  • 理論的には 融点の3倍くらいです
  • この理論上の限界に達するのを妨げる中間的な不安定化事件 (災害) が起こります.

研究 の 目的:

  • 超熱結晶の安定性の限界を 実験的に調べるため
  • 極限条件下での"エントロピー災害"の限界をテストする.
  • 溶解のダイナミクスを探すために

主な方法:

  • 超高速加熱技術を使用した.
  • 格子温度を追跡するために高解像度の無弾性X線散射を使用した.
  • 極度の温度条件下で実験的にテストされた金.

主要な成果:

  • 金の試料は 溶解点の14倍以上まで加熱されながら 結晶の構造が保たれました
  • 観測された超高温の限界は予測された"エントロピー災害"の限界を大幅に超えた.
  • 試料は研究された非常に短い時間スケールで拡大せず,以前の見積もりとは異なる.

結論:

  • 実験結果は,固体における過熱の限界がかなり高く,あるいは存在しない可能性を示唆している.
  • 超高速加熱条件と時間スケール効果は,超高温ダイナミクスの重要な要因です.
  • この研究は,固体物質の安定性の基本的限界についての新しい洞察を提供します.