ダブルからシングル層への変換を含むトポケミカル反応:Mo3Ta2O10Nとカゴメラット

Ryoya Higuchi1, Kohdai Ishida1, Cédric Tassel1,2

  • 1Department of Energy and Hydrocarbon Chemistry, Graduate School of Engineering, Kyoto University, Nishikyo-ku, Kyoto 615-8510, Japan.

まとめ

この研究は,Mo2Ta2O11における新しいトポケミカル反応を明らかにし,四面体層の崩壊によってユニークなMoベースのカゴメ格子 (Mo3Ta2O10N) を生み出しています. この前例のない構造的再編成は 超安定物質合成の可能性を広げています

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