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Updated: Sep 13, 2025

Line Shape Analysis of Dynamic NMR Spectra for Characterizing Coordination Sphere Rearrangements at a Chiral Rhenium Polyhydride Complex
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ディスタル・スキャフォルドの柔軟性は,Eyringの活性化パラメータをRe(I) 置換反応で調節する:ダイナミクスを"主題的第3の協調球"として用いるケース

Alec T Larson1, Serhii Vasylevskyi1, Michael J Rose1

  • 1Department of Chemistry, University of Texas at Austin, Austin, 105 E 24th St, Austin, Texas 78712, United States.

Journal of the American Chemical Society
|July 29, 2025
PubMed
まとめ

金属複合体のダイナミックリガンド・スカファードは,反応性を著しく高めます. この研究は,チューニングリガンドの柔軟性が,反応性研究を簡素化することによって,より反応性の高い金属複合体を作成するための新しい設計原理を提供することを示しています.

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