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Updated: Sep 12, 2025

Efficient Synthesis of All-Carbon Quaternary Centers via the Conjugate Addition of Functionalized Monoorganozinc Bromides
07:50

Efficient Synthesis of All-Carbon Quaternary Centers via the Conjugate Addition of Functionalized Monoorganozinc Bromides

Published on: May 26, 2019

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固体高次亜鉛酸の適用により,Ni/ラサレッタ-リガンド触媒による,アトロセレクティブネギシ交配反応が可能になる

Damian Groß1, Lennart Kirchhoff1, Benedikt Schiller1

  • 1Department Chemie, Ludwig-Maximilians-Universität München, Butenandtstraße 5-13, Haus F, 81377 München, Germany.

Journal of the American Chemical Society
|August 5, 2025
PubMed
まとめ

新しいアトロポセレクティブ・ネギシ・クロスカップリング反応は,固体高位亜鉛酸とニッケル触媒を用いて,高収量と純度を持つ有価なアトロポイソメアビアリルを生成する. この方法は複雑なキラル分子の合成を可能にします.

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