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Updated: Sep 8, 2025

Accessing Valuable Ligand Supports for Transition Metals: A Modified, Intermediate Scale Preparation of 1,2,3,4,5-Pentamethylcyclopentadiene
09:45

Accessing Valuable Ligand Supports for Transition Metals: A Modified, Intermediate Scale Preparation of 1,2,3,4,5-Pentamethylcyclopentadiene

Published on: March 20, 2017

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連続CC,C-C機能化反応によるビサイクロ[1.1.1]ペンタンの直接合成

Joshua K Sailer1, Duc Ly1, Djamaladdin G Musaev1,2

  • 1Department of Chemistry, Emory University, 1515 Dickey Drive, Atlanta, Georgia 30322, United States.

Journal of the American Chemical Society
|August 14, 2025
PubMed
まとめ

研究者は,連続したカルベンの反応を用いて,新しい2代置換ビサイクロ[1.1.1]ペンタンを合成した. この方法は,ユニークなダイラジカル加算メカニズムを通じて,貴重なビサイクロ[1.1.1]ペンタンのエスカファードへの迅速なアクセスを提供します.

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