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Alkyl Halides02:45

Alkyl Halides

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Structural Properties
Alkyl halides are halogen-substituted alkanes wherein one or more hydrogen atoms of an alkane is replaced by a halogen atom such as fluorine, chlorine, bromine, or iodine. The carbon atom in an alkyl halide is bonded to the halogen atom, which is sp3-hybridized and exhibits a tetrahedral shape.
Unlike alkyl halides, compounds in which a halogen atom is bonded to an sp2 -hybridized carbon atom of a carbon-carbon double bond (C=C) are called vinyl halides. Whereas aryl...
17.4K
Halogenation of Alkenes02:46

Halogenation of Alkenes

16.5K
Halogenation is the addition of chlorine or bromine across the double bond in an alkene to yield a vicinal dihalide. The reaction occurs in the presence of inert and non-nucleophilic solvents, such as methylene chloride, chloroform, or carbon tetrachloride.
Consider the bromination of cyclopentene. Molecular bromine is polarized in the proximity of the π electrons of cyclopentene. An electrophilic bromine atom adds across the double bond, forming a cyclic bromonium ion intermediate.
16.5K
Polymer Classification: Architecture01:14

Polymer Classification: Architecture

2.9K
Polymers are classified as linear or branched on the basis of their chain architecture. The polymer chains in linear polymers have a long chain-like structure with minimal to no branching at all. Even if a polymer features large substituent groups on the monomer, which appear as branches to the skeleton, it is not considered a branched polymer. A branched polymer contains secondary polymer chains that arise from the main polymer chain. The branching occurs when the polymer growth shifts from...
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Halogens03:01

Halogens

19.0K
Group 17 elements, known as halogens, are nonmetals. At room temperature, fluorine and chlorine are gases, bromine is a liquid, and iodine a solid. Astatine is a highly unstable radioactive element, so currently, most of its properties are unknown due to its short half-life. Tennessine is a synthetic element also predicted to be in this group. 
19.0K
Electrophilic Addition to Alkynes: Hydrohalogenation02:35

Electrophilic Addition to Alkynes: Hydrohalogenation

10.3K
Electrophilic addition of hydrogen halides, HX (X = Cl, Br or I) to alkenes forms alkyl halides as per Markovnikov's rule, where the hydrogen gets added to the less substituted carbon of the double bond. Hydrohalogenation of alkynes takes place in a similar manner, with the first addition of HX forming a vinyl halide and the second giving a geminal dihalide.
10.3K
Electrophilic 1,2- and 1,4-Addition of X2 to 1,3-Butadiene01:14

Electrophilic 1,2- and 1,4-Addition of X2 to 1,3-Butadiene

2.8K
Electrophilic addition of halogens to alkenes proceeds via a cyclic halonium ion to form a 1,2-dihalide or a vicinal dihalide.
2.8K
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  2. 安全なエネルギー貯蔵のためのポリエチレングリコールベースの阻燃相変化材料の共性ハロゲン化

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Solid-state Graft Copolymer Electrolytes for Lithium Battery Applications
05:33

Solid-state Graft Copolymer Electrolytes for Lithium Battery Applications

Published on: August 12, 2013

21.8K

安全なエネルギー貯蔵のためのポリエチレングリコールベースの阻燃相変化材料の共性ハロゲン化

Long Geng1, Guangyuan Liang1, Xiao Zhang1

  • 1School of Low-carbon Energy and Power Engineering, China University of Mining and Technology, Beijing, China.

iScience
|August 21, 2025

PubMed で要約を見る

まとめ
この要約は機械生成です。

この研究では,熱調節と炎症阻害性を改善するために,ブロミンによる相変化材料 (PCM) を設計した. 改造されたPCMは,高度なアプリケーションのための強化された温度制御,燃焼の減少,および自己治癒特性を示しています.

キーワード:
材料の適用材料の特徴材料合成

さらに関連する動画

From Molecules to Materials: Engineering New Ionic Liquid Crystals Through Halogen Bonding
06:44

From Molecules to Materials: Engineering New Ionic Liquid Crystals Through Halogen Bonding

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Fabricating Degradable Thermoresponsive Hydrogels on Multiple Length Scales via Reactive Extrusion, Microfluidics, Self-assembly, and Electrospinning
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Fabricating Degradable Thermoresponsive Hydrogels on Multiple Length Scales via Reactive Extrusion, Microfluidics, Self-assembly, and Electrospinning

Published on: April 16, 2018

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関連する実験動画

Solid-state Graft Copolymer Electrolytes for Lithium Battery Applications
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Solid-state Graft Copolymer Electrolytes for Lithium Battery Applications

Published on: August 12, 2013

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From Molecules to Materials: Engineering New Ionic Liquid Crystals Through Halogen Bonding
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From Molecules to Materials: Engineering New Ionic Liquid Crystals Through Halogen Bonding

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Fabricating Degradable Thermoresponsive Hydrogels on Multiple Length Scales via Reactive Extrusion, Microfluidics, Self-assembly, and Electrospinning
12:07

Fabricating Degradable Thermoresponsive Hydrogels on Multiple Length Scales via Reactive Extrusion, Microfluidics, Self-assembly, and Electrospinning

Published on: April 16, 2018

13.6K

科学分野:

  • 材料科学
  • 化学工学
  • ポリマー化学

背景:

  • 段階変化材料 (PCM) は熱エネルギー貯蔵に不可欠ですが,しばしば固有の炎症阻害性が欠けています.
  • PCMにおける相変化特性と炎阻害性を同時に最適化することは大きな課題です.

研究 の 目的:

  • PCMの相変化特性を同時に調節し,燃焼阻害性能を向上させるための分子工学戦略を開発する.
  • PCMにおけるブロム化改変の二重機能性を調査する.

主な方法:

  • PCMのヒドロキシルサイトをブロム原子で共振的に改変する.
  • 段階変化特性 (温度,潜在的熱) と燃焼阻害性能 (燃焼指標) の表記

主要な成果:

  • ブロムの改変により相変化温度が調整され,範囲が10.72%拡大され,潜在熱が影響された.
  • 耐火性の指標は著しく低下し,CO2のピーク出力は39.55%,燃焼熱の最大有効量は19.85%,平均熱放出率は9.17%減少した.
  • 改造されたPCMは 柔軟性と自己治癒能力を示しました

結論:

  • 分子レベルでのブロム化置換は,PCMにおける相変化調節と炎症阻害のバランスをとるための統一された化学的枠組みを提供します.
  • このアプローチは次世代の多機能PCMを開発するための有望な戦略です.
  • 潜在的応用には,バッテリー熱管理と建物の隔熱が含まれます.