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Updated: Sep 10, 2025

Facile Preparation of 2Z,4E-Dienamides by the Olefination of Electron-deficient Alkenes with Allyl Acetate
06:46

Facile Preparation of 2Z,4E-Dienamides by the Olefination of Electron-deficient Alkenes with Allyl Acetate

Published on: June 21, 2017

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ビサイクロ[1.1.0]ブタンとα,β-不飽和アルデヒドのアミノ触媒エナンチオセレクティブ [2 + 2]サイクル添加

René Slot Bitsch1, Enrico Marcantonio1, Erlaitz Basabe Obregón1

  • 1Department of Chemistry, Aarhus University 8000 Aarhus C Denmark kaj@chem.au.dk.

Chemical science
|August 21, 2025
PubMed
まとめ

この研究は,エナチオセレクティブ [2 + 2] サイクル添加によるビサイクロ[2.1.1]ヘクサンの合成のための新しいアミノ触媒法を導入する. この反応は,ビサイクロ[1.1.0]ブタンを様々なα,β不飽和アルデヒドと効率的に結合させ,貴重な化学的構造を作り出します.

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