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Updated: Sep 10, 2025

Facile and Efficient Preparation of Tri-component Fluorescent Glycopolymers via RAFT-controlled Polymerization
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ARGET-ATRPで製造される制御されたフッ素ポリマーのサイドチェーンの役割

Yadong Yang1, Fuchun Zhao1, Hong Zhang1

  • 1School of Materials Science and Engineering, Key Laboratory of Advanced Materials of Tropical Island Resources, Ministry of Education, Hainan University, Haikou 570228, China.

International journal of biological macromolecules
|August 21, 2025
PubMed
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研究者が改良した天然ゴム

キーワード:
ARGET-ATRP についてフッ素アクリレート分子ネットワーク天然ゴム

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Polymer Classification: Architecture

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The skeletal structure of polymers synthesized via radical polymerization is always branched. For example, the polymerization of ethylene by radical polymerization results in a low-density grade of polyethylene with a heavily branched skeletal structure. Here, the radical site abstracts hydrogen from the growing chain, and the radical site shifts from the end (a primary carbon center) to anywhere within the growing chain (a secondary carbon center). Consequently, the part of the chain from the...
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Chain-growth or addition polymerization is successive addition reactions of monomers with a polymer chain. In radical chain-growth polymerization, the reaction proceeds via a free-radical intermediate. The free radical is formed from radical initiators, which spontaneously generate free radicals by homolytic fission. Organic peroxides (such as dibenzoyl peroxide, as shown in Figure 1) or azo compounds are popular radical initiators. A low concentration ratio of radical initiator to monomer is...
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