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Updated: Sep 10, 2025

Synthesis of Hypervalent Iodonium Alkynyl Triflates for the Application of Generating Cyanocarbenes
12:27

Synthesis of Hypervalent Iodonium Alkynyl Triflates for the Application of Generating Cyanocarbenes

Published on: September 8, 2013

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アリル/ビニルハリドとトリフラートのフォーマット媒介C−C結合:カルボニルアリレーションと還元クロスカップリング

Yu-Hsiang Chang1, Yoon Cho1, Weijia Shen1

  • 1University of Texas at Austin, Department of Chemistry Welch Hall (A5300), 105 E 24th St., Austin, TX 78712, USA.

ACS catalysis
|August 22, 2025
PubMed
まとめ

この研究は,アリル/ビニルハライドの触媒方法を提供する,フォーマット媒介のC−C結合反応をカタログ化している. これらの反応は,水素源として豊富なホルマートを使用して,プレメタル化反応剤を避けます.

キーワード:
C-C カップリングキノコ酸緑の化学水素転送削減する

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Simple aryl halides do not react with nucleophiles. However, nucleophilic aromatic substitutions can be forced under certain conditions, such as high temperatures or strong bases. The mechanism of substitution under such conditions involves the highly unstable and reactive benzyne intermediate. Benzyne contains equivalent carbon centers at both ends of the triple bond, each of which is equally susceptible to nucleophilic attack. This 50–50 distribution of products is...
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