毛細な媒体の表面蒸発と進化:柱配列マイクロモデルの研究
1Institute of Rock and Soil Mechanics, Chinese Academy of Sciences, Wuhan, Hubei 430071, China; State Key Laboratory of Geomechanics and Geotechnical Engineering Safety, Wuhan, Hubei 430071, China; University of Chinese Academy of Sciences, Beijing 100049, China.
Journal of colloid and interface science
|August 24, 2025
まとめ
狭い毛穴での蒸発は 毛穴の大きさだけでなく インターフェースの形によって制御されます 毛穴スケールの液体蒸気界面を理解することで,土壌水文学と海水淡化モデルが改善されます.
科学分野:
- 毛細な媒体の物理
- 多相流量
- インターフェース現象
背景:
- 狭い毛穴での蒸発は,土壌の塩化と塩分除去に不可欠です.
- 従来のモデルでは,空気侵入後の液体-蒸気インターフェースの ダイナミックな進化を無視しています
- 孔の閉じ込めとインターフェースの形状は,局所的な蒸発率に大きな影響を与えます.
研究 の 目的:
- 蒸発速度に対する毛穴の閉じ込めとインターフェース形態の影響を調査する.
- 毛細な媒体の相変化を予測するためのメカニズム的枠組みを開発する.
主な方法:
- 2Dの多孔メディアアナログとして柱配列マイクロモデルを使用した.
- リアルタイムの可視化と高解像度画像処理を使用しています.
- 界面領域と曲線の定量化された時空的変動.
主要な成果:
- 外部インタフェースは相変化の85~92%を占め,内部インタフェースは15%未満であった.
- 蒸発運動は,交差点の曲率半径が減少するにつれて指数関数的に増加した.
- 特徴的な界面曲率長さスケール (1~50μm) が蒸発速度を決定した.
結論:
- 孔の閉じ込めと界面の幾何学は蒸発運動を高めます
- 発見は,より小さな毛穴での蒸発の表面的な抑制を明らかにします.
- インターフェイス幾何学を,多孔性媒体の相変化予測に結びつけるメカニズム的枠組みを確立した.
関連する概念動画
Theories of Dissolution: The Danckwerts' Model and Interfacial Barrier Model
433
Various dissolution theories provide insight into the factors that influence the dissolution rate. Danckwerts' Model suggests that turbulence, rather than a stagnant layer, characterizes the dissolution medium at the solid-liquid interface. In this model, the agitated solvent contains macroscopic packets that move to the interface via eddy currents, facilitating the absorption and delivery of the drug to the bulk solution. The regular replenishment of solvent packets maintains the...
433
Capillarity in Fluid
386
Capillarity describes the movement of liquid in small spaces without external forces acting on it. The capillarity is driven by surface tension and adhesive interactions between the liquid and surrounding solid surfaces. This effect is often seen in narrow tubes, porous materials, and fine particles.
Surface tension is crucial to capillarity. It results from cohesive forces between liquid molecules at the liquid-air boundary, forming a skin that resists external forces. When the capillary tube...
Surface tension is crucial to capillarity. It results from cohesive forces between liquid molecules at the liquid-air boundary, forming a skin that resists external forces. When the capillary tube...
386
Phase Transitions: Vaporization and Condensation
18.4K
The physical form of a substance changes on changing its temperature. For example, raising the temperature of a liquid causes the liquid to vaporize (convert into vapor). The process is called vaporization—a surface phenomenon. Vaporization occurs when the thermal motion of the molecules overcome the intermolecular forces, and the molecules (at the surface) escape into the gaseous state. When a liquid vaporizes in a closed container, gas molecules cannot escape. As these gas phase...
18.4K
Interfacial Electrochemical Methods: Overview
385
Interfacial electrochemical methods focus on the phenomena occurring at the boundary between an electrode and a solution, as opposed to bulk methods that concentrate on the solution's overall properties. These interfacial methods are classified as either static or dynamic based on the presence of a nonzero current in the electrochemical cell and the consistency of analyte concentrations. Static methods, such as potentiometry, measure the cell's potential without any significant current...
385
Theories of Dissolution: Diffusion Layer Model
932
Dissolution, the process by which drug particles dissolve in a solvent, is explained by the diffusion layer model, a theoretical framework that simulates the absorption of oral drugs and allows us to analyze experimental data.
This process starts with a thin layer, saturated with the drug, forming at the interface between the solid and liquid. The solute then diffuses from this layer into the main solution. The Noyes-Whitney equation suggests that the rate of dissolution relies on the diffusion...
This process starts with a thin layer, saturated with the drug, forming at the interface between the solid and liquid. The solute then diffuses from this layer into the main solution. The Noyes-Whitney equation suggests that the rate of dissolution relies on the diffusion...
932
Vapor Pressure of Fluid
1.5K
The vapor pressure of a fluid is a crucial concept in fluid mechanics, influencing phenomena such as boiling and cavitation. Vapor pressure refers to the pressure exerted by a vapor at a state of thermodynamic equilibrium with its corresponding liquid phase at a specific temperature. It represents the tendency of molecules to escape from the fluid surface into the vapor phase.
When a liquid is placed in a closed container with a small air space, and the space is evacuated, vapor molecules will...
When a liquid is placed in a closed container with a small air space, and the space is evacuated, vapor molecules will...
1.5K


