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Updated: Sep 10, 2025

Microfluidic-based Synthesis of Covalent Organic Frameworks COFs: A Tool for Continuous Production of COF Fibers and Direct Printing on a Surface
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Microfluidic-based Synthesis of Covalent Organic Frameworks COFs: A Tool for Continuous Production of COF Fibers and Direct Printing on a Surface

Published on: July 10, 2017

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配合性有機フレームワークの伝導性織り込みは,スピン密度,軌道再編,および優れた光反応性のための電荷移動性を操作する

Qian-Qian Huang1, Ning Li1, Man-Shi Han1

  • 1Guangdong Provincial Key Laboratory of Carbon Dioxide Resource Utilization, School of Chemistry, South China Normal University, Guangzhou, Guangdong, 510006, China.

Angewandte Chemie (International ed. in English)
|August 26, 2025
PubMed
まとめ

この研究は,キナゾリノンの光合成の光触媒効率を大幅に高める,チオフェン改変による新しい3D共性有機フレームワーク (COF) を導入した. 革新的な設計により,伝導性とアクティブサイトアクセシビリティが向上し,従来のCOFの主要な限界を克服します.

キーワード:
導電性協和有機フレームワーク層間編み物光触媒

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Cycloheptatriene is a neutral monocyclic unsaturated hydrocarbon that consists of an odd number of carbon atoms and an intervening sp3 carbon in the ring. The three double bonds in the ring correspond to 6 π electrons, which is a Huckel number, and therefore satisfies the criteria of 4n + 2 π electrons. However, the intervening sp3 carbon disrupts the continuous overlap of p orbitals. As a result, cycloheptatriene is not aromatic.
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