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Updated: Sep 10, 2025

Controlled Photoredox Ring-Opening Polymerization of O-Carboxyanhydrides Mediated by Ni/Zn Complexes
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ライトプロモートされたC-C) ダイアルキルNiII複合体からの還元性除去

Alexander Q Cusumano1, Braden C Chaffin1, David A Cagan2

  • 1Department of Chemistry and Biochemistry, University of California Los Angeles, Los Angeles, California 90095, United States.

Journal of the American Chemical Society
|August 26, 2025
PubMed
まとめ

光の活性化により,ニッケル触媒によるC ((sp3) -C ((sp3)) 結合形成が可能になり,Ni (((II)) 複合体からの困難な還元性除去を克服する. この光分解/急性反射メカニズムは,難しいクロスカップリング反応のための新しい戦略を提供します.

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