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Updated: Sep 10, 2025

Preparation of Stable Bicyclic Aziridinium Ions and Their Ring-Opening for the Synthesis of Azaheterocycles
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Preparation of Stable Bicyclic Aziridinium Ions and Their Ring-Opening for the Synthesis of Azaheterocycles

Published on: August 22, 2018

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アゾメチンイライドとジメチルアセチレンカルボキシラートの (3 + 2) サイクル添加に関するメカニズム的洞察

Mohamed Chellegui1,2, Raghad Mowafak Al-Mokhtar3, Raad Nasrullah Salih4

  • 1Laboratory of Organic Chemistry (LR17ES08), Faculty of Sciences, University of Sfax Sfax 3038 Tunisia.

RSC advances
|August 27, 2025
PubMed
まとめ

この研究は,密度関数理論を用いてアゾメチンイライドとジメチルアセチレンデカルボキシラート間の (3+2) サイクル添加メカニズムを解明する. 反応は極性で運動制御された経路で進行し,内分選択性を好む.

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