強化コンクリートにおける腐食破裂のシミュレーション 多相多種電気化学相場モデリング
Tianhao Yao1, Houmin Li1, Keyang Wu2
1School of Civil Engineering, Architecture and the Environment, Hubei University of Technology, Wuhan 430068, China.
Materials (Basel, Switzerland)
|August 28, 2025
まとめ
この研究では,リバーの腐食によるコンクリートのクラッキングをシミュレートするための多種電気化学フェーズフィールドモデルを導入します. 構造の耐久性を評価するのに役立ちます.
科学分野:
- 材料科学
- 土木工学
- 電気化学
背景:
- 鉄筋コンクリートの不均一な腐食破裂は,構造の耐久性の障害の主な原因です.
- 材料の寿命を予測するには,腐食,生の膨らみ,裂けの結合メカニズムを理解することが重要です.
研究 の 目的:
- 鉄筋コンクリートの腐食誘発のクラッキングをシミュレートし分析するために,顕微鏡スケールの多種電気化学フェーズフィールドモデルを開発する.
- 電気化学反応の時空結合,イオン輸送,そして断裂力学を研究する.
主な方法:
- 統合された電気化学反応動力学,マルチイオン輸送,および相場破裂理論.
- 電気化学的過程と生の膨らみと亀裂の拡散を関連付ける重要な変数として,局所的な腐食電流の密度を利用した.
- 断裂開始と伝播分析のために使用された相場シミュレーション.
主要な成果:
- このモデルは,実験データによって検証された,クラッキングの持続時間,クラッキングの形,およびイオン濃度の分布を正確に予測します.
- 局所的な腐食電流密度は,電気化学反応速度を効果的に示す.
- パラメトリック研究では,様々な要因 (例えば,酸素の拡散,保護層の厚さ) が裂け目パターンに及ぼす影響が明らかになった.
結論:
- 開発されたマルチ物理モデルは,鉄筋コンクリートの腐食誘発裂解を分析するための堅固な枠組みを提供します.
- 定量分析,耐久性評価,コンクリート構造物の保護設計のための理論的ツールを提供します.
関連する概念動画
Corrosion of Reinforcement
252
The corrosion of steel reinforcement within concrete is a process influenced by the material's inherent properties and external factors. The high pH level of around 13, provided by calcium hydroxide present in concrete, initially protects the steel reinforcement by promoting the formation of a passive iron oxide layer on its surface.
However, over time and under certain conditions like carbonation, chloride ingress, and cracking this protective state can be compromised. Steel has areas with...
However, over time and under certain conditions like carbonation, chloride ingress, and cracking this protective state can be compromised. Steel has areas with...
252
Microcracking in Concrete
205
Microcracking in concrete refers to the tiny cracks that can form within the material even before any external load is applied. These microcracks typically occur at the interface between the coarse aggregate and the hydrated cement paste, often as a result of differential volume changes prompted by variations in stress-strain behavior, as well as thermal and moisture movement. Initially, these microcracks remain stable and do not grow substantially until the concrete is stressed to about 30...
205
Types of Non-structural Cracks in Concrete
244
Non-structural cracks are primarily of three types: plastic, early-age thermal, and drying shrinkage cracks. Plastic cracks are further classified into plastic shrinkage cracks and plastic settlement cracks.
Plastic shrinkage cracks typically form within hours after the concrete is poured. The concrete's surface dries faster than the bottom, creating tensile stress that the still-plastic concrete cannot withstand, leading to diagonal or randomly patterned cracks on the concrete surface.
Plastic shrinkage cracks typically form within hours after the concrete is poured. The concrete's surface dries faster than the bottom, creating tensile stress that the still-plastic concrete cannot withstand, leading to diagonal or randomly patterned cracks on the concrete surface.
244
Sulfate Attack on Concrete
289
Sulfate attack on concrete is a deterioration process characterized by a whitish discoloration beginning at the edges and corners, accompanied by cracking and spalling. This phenomenon occurs when sulfates react with the components of hardened concrete, forming compounds like calcium sulfate and calcium sulfoaluminate which occupy more space than the substances they replace, causing the concrete to expand and disrupt.
Sulfates from sources like soil, groundwater, or industrial effluents...
Sulfates from sources like soil, groundwater, or industrial effluents...
289
Acid Attack on Concrete
327
When acids come into contact with concrete, they initiate a chemical reaction that dissolves the hydrated cement paste. This process leads to softening and structural weakening of the concrete. This issue is commonly observed in environments such as chimneys, sewers, and industrial settings. The severity of the damage increases as the pH of the water interacting with the concrete drops below 6.5. In particular, a pH under 4.5 can cause significant concrete damage.
The rate at which hydrogen...
The rate at which hydrogen...
327
Effect of Sea Water on Concrete
425
Concrete exposed to seawater can undergo degradation like the dissolution of ettringite and gypsum, increasing the material's porosity and decreasing its strength. In contrast, the crystallization of salts within the concrete's pores can cause expansion, particularly above the waterline where evaporation occurs. Nonetheless, this expansion only happens when seawater, enabled by the concrete's permeability, manages to infiltrate the structure.
Concrete in areas between tide marks,...
Concrete in areas between tide marks,...
425


