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Updated: Sep 9, 2025

The Synthesis, Characterization and Reactivity of a Series of Ruthenium N-triphosPh Complexes
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The Synthesis, Characterization and Reactivity of a Series of Ruthenium N-triphosPh Complexes

Published on: April 10, 2015

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フォスファノフェノラートベースの希土金属-銅複合体の合成と特徴付け

Andreas Fleißner1, Viktoria Rehbein1, Alexandra Haidinger1

  • 1Institute of Inorganic Chemistry, Graz University of Technology, Stremayrgasse 9, 8010 Graz, Austria.

Inorganic chemistry
|August 28, 2025
PubMed
まとめ

この研究は,フォスフィンフェノラートリガンドを使用して,新しい二核稀土金属 (III) -銅 (I) コンプレクスを合成します. 代替の経路は効果が低いが,トリフラート交換反応は新しいテルト-ブトオキシド複合体を産生した.

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Metal ions can be separated from one another by complexation with organic ligands–the chelating agent– to form uncharged chelates. Here, the chelating agent must contain hydrophobic groups and behave as a weak acid, losing a proton to bind with the metal. Since most organic ligands used in this process are insoluble or undergo oxidation in the aqueous phase, the chelating agent is initially added to the organic phase and extracted into the aqueous phase. The metal-ligand complex is...
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