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Updated: Sep 9, 2025

[DPEPhosbcpCu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst
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[DPEPhosbcpCu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst

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アルキンとビニル・フォスフォナートのレジオ・およびステレオ選択的還元結合のためのフォトレドックス/ニッケル二重触媒

Radhakrishnan Sakthiganapathi1, Dhanip Kumar Sharma1, Rituparna Dutta1

  • 1Department of Chemistry, SRM University-AP, Amaravati, Andhra Pradesh 522240, India.

The Journal of organic chemistry
|August 29, 2025
PubMed
まとめ

この研究は,アルキンとビニルフォスフォナートの効率的な二重触媒的還元結合を導入する. この反応は,メタノールが陽子源として作用する同位リン酸塩の選択的合成を提供します.

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Reduction of Alkynes to cis-Alkenes: Catalytic Hydrogenation

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Catalytic hydrogenation of alkenes is a transition-metal catalyzed reduction of the double bond using molecular hydrogen to give alkanes. The mode of hydrogen addition follows syn stereochemistry.
The metal catalyst used can be either heterogeneous or homogeneous. When hydrogenation of an alkene generates a chiral center, a pair of enantiomeric products is expected to form. However, an enantiomeric excess of one of the products can be facilitated using an enantioselective reaction or an...
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