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Updated: Sep 9, 2025

Accessing Valuable Ligand Supports for Transition Metals: A Modified, Intermediate Scale Preparation of 1,2,3,4,5-Pentamethylcyclopentadiene
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Accessing Valuable Ligand Supports for Transition Metals: A Modified, Intermediate Scale Preparation of 1,2,3,4,5-Pentamethylcyclopentadiene

Published on: March 20, 2017

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ベンジルアルキニルエーテルとカスケード反応の計算により設計されたディヒドロインデノン型再配置

Keisuke Fukaya1, Kaoru Tanaka1, Ryo Karashimada1

  • 1Biotechnology Research Center and Department of Biotechnology, Toyama Prefectural University, 5180 Kurokawa, Imizu, Toyama 939-0398, Japan.

Organic letters
|August 29, 2025
PubMed
まとめ

コンピューターによる設計により,新種のオロマティブ・クライゼン型再配置が可能になり,四次炭素が生成された. この反応は,特定のエーテルに適用され,複雑な三循環系とダイヒドロインデノンの誘導体を生成した.

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