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Updated: Sep 9, 2025

Efficient Synthesis of All-Carbon Quaternary Centers via the Conjugate Addition of Functionalized Monoorganozinc Bromides
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Efficient Synthesis of All-Carbon Quaternary Centers via the Conjugate Addition of Functionalized Monoorganozinc Bromides

Published on: May 26, 2019

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ジルコノセンとフォトレドックス触媒によって活性化されていないアルキル塩化物の塩素原子移転

Toshimasa Okita1, Kazuhiro Aida1, Keisuke Tanaka1

  • 1Department of Applied Chemistry, Waseda University, 513 Wasedatsurumakicho, Shinjuku, Tokyo 162-0041, Japan.

Precision chemistry
|August 29, 2025
PubMed
まとめ

この研究は,活性化されていないアルキル塩化物から炭素ラジカルを生成するためにジルコノセンとフォトレドックス触媒を用いた新しい触媒法を導入しています. このアプローチにより,複雑な分子に対する軽度の水素化およびボリル化反応が可能になる.

キーワード:
アルキル塩化物ボリレーションハロゲン原子移転フォトレドックス触媒ジルコノセーン

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