関連する実験動画

Updated: Sep 9, 2025

Preparation of a Corannulene-functionalized Hexahelicene by CopperI-catalyzed Alkyne-azide Cycloaddition of Nonplanar Polyaromatic Units
09:35

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Published on: September 18, 2016

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銅と金で触媒化されたディビニラレンを制御可能なサイクルでポリサイクリックN-ヘテロサイクルの異なる合成

Mi Li1, Shi-Jie Liu2, Kua-Fei Wei1

  • 1College of Science, Henan Agricultural University, Zhengzhou 450002, China.

JACS Au
|August 29, 2025
PubMed
まとめ

銅の触媒は,ディビニラレンから新しいN-ヘテロサイクルの合成を可能にし,貴金属に多用途の代替品を提供します. この研究は,金属カルベンの化学を,触媒制御の選択性および原子経済反応で拡張する.

キーワード:
1,2-N 移行銅脱対称化ディビニラレンドナー/ドナーカルベン

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Cycloadditions are one of the most valuable and effective synthesis routes to form cyclic compounds. These are concerted pericyclic reactions between two unsaturated compounds resulting in a cyclic product with two new σ bonds formed at the expense of π bonds. The [4 + 2] cycloaddition, known as the Diels–Alder reaction, is the most common. The other example is a [2 + 2] cycloaddition.
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