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Updated: Sep 9, 2025

Cercosporin-Photocatalyzed [4+1]- and [4+2]-Annulations of Azoalkenes Under Mild Conditions
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Cercosporin-Photocatalyzed [4+1]- and [4+2]-Annulations of Azoalkenes Under Mild Conditions

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協同的二次有機触媒非対称性デカルボキシル [4 + 3] ベンゾキサジナノンによる無効化

Ling Zhu1, Teng Xie1, Jin Song2

  • 1Hefei National Laboratory for Physical Sciences at the Microscale and Department of Chemistry, University of Science and Technology of China, Hefei 230026, China.

Precision chemistry
|August 29, 2025
PubMed
まとめ

新しい協同触媒法では,ルイス基とキラルN-ヘテロサイクリックカルベン (NHC) を用いてエナチオ選択的無効化を行う. このアプローチは基板の範囲を拡大し,多様なスピロキシンドールへの直接的な経路を提供します.

キーワード:
[4 + 3] キャンセルベンゾクサジナノンキラルN-ヘテロサイクリックカルベン協同触媒スピロベンザゼピノン

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