関連する実験動画

Updated: Sep 9, 2025

Efficient Synthesis of All-Carbon Quaternary Centers via the Conjugate Addition of Functionalized Monoorganozinc Bromides
07:50

Efficient Synthesis of All-Carbon Quaternary Centers via the Conjugate Addition of Functionalized Monoorganozinc Bromides

Published on: May 26, 2019

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オーガノカタリティック・エナチオセレクティブ [4 + 4] フーラン・オルトキノディメタン・サイクル添加物

Niklas Lawaetz Østergaard1, Anne Kristensen1, Enrico Marcantonio1

  • 1Department of Chemistry, Aarhus University, Aarhus C, 8000, Denmark.

Angewandte Chemie (International ed. in English)
|August 30, 2025
PubMed
まとめ

この研究は,フラン誘導体からサイクロオクタノイドを生成するための最初の有機触媒エナンチオセレクティブ [4+4] サイクロアディションを導入する. 複雑な有機分子への新しい経路を提供することで,高収量とエナチオ選択性を達成します.

キーワード:
非対称合成サイクル添加フュージッドリングシステムヘテロサイクル器官触媒

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