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Updated: Sep 9, 2025

A 'Plug and Play' Method to Create Water-dispersible Nanoassemblies Containing an Amphiphilic Polymer, Organic Dyes and Upconverting Nanoparticles
12:51

A 'Plug and Play' Method to Create Water-dispersible Nanoassemblies Containing an Amphiphilic Polymer, Organic Dyes and Upconverting Nanoparticles

Published on: November 14, 2015

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安定性と光感性を強化したコロイド発光ナノ結晶のためのオレフィン・リガンド・メタテシス

Seongbeom Yeon1, Yoseph Kim2, Abdessamad El Adel3

  • 1Department of Materials Science and Engineering, Korea Advanced Institute of Science and Technology (KAIST), 291 Daehak-ro, Yuseong-gu, Daejeon, 34141, Republic of Korea.

Angewandte Chemie (International ed. in English)
|August 30, 2025
PubMed
まとめ

研究者はディスプレイ用のペロブスキートナノ結晶 (PNC) を改良するための新しい方法を開発しました. このオレフィンメタテシス技術は,安定性と光感性を高め,より少ない紫外線で高解像度のパターニングを可能にします.

キーワード:
コロイド発光ナノ結晶直接光学パターニングリガンド化学オレフィンの転移ペロフスキート

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Olefin Metathesis Polymerization: Overview

Recently, the development of olefin metathesis polymerization advanced the field of polymer synthesis. Simply put, the reorganization of substituents on their double bonds between two olefins in the presence of a catalyst is known as the olefin metathesis reaction. The use of metathesis reaction for polymer synthesis is called olefin metathesis polymerization.
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Acyclic diene metathesis polymerization or ADMET polymerization involves cross-metathesis of terminal dienes, such as 1,8-nonadiene, to give linear unsaturated polymer and ethylene. As ADMET is a reversible process, the formed ethylene gas must be removed from the reaction mixture to complete the polymerization process.
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Some cycloaddition reactions are activated by heat, while others are initiated by light. For example, a [2 + 2] cycloaddition between two ethylene molecules occurs only in the presence of light. It is photochemically allowed but thermally forbidden.
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