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Updated: Sep 9, 2025

Morphology Control for Fully Printable Organic–Inorganic Bulk-heterojunction Solar Cells Based on a Ti-alkoxide and Semiconducting Polymer
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Morphology Control for Fully Printable Organic–Inorganic Bulk-heterojunction Solar Cells Based on a Ti-alkoxide and Semiconducting Polymer

Published on: January 10, 2017

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有機太陽電池の固体添加イソメリゼーション工学によるドナーと受容体の集積行動を選択的に調節し,効率が20%を超えています

Keli Shi1, Haicui Liu1, Shucheng Qin2

  • 1Key Laboratory of Solid State Optoelectronic Devices of Zhejiang Province, College of Physics and Electronic Information Engineering, Zhejiang Normal University, Jinhua, Zhejiang, 321004, China.

Angewandte Chemie (International ed. in English)
|September 1, 2025
PubMed
まとめ

研究者は,有機太陽電池 (OSC) 膜形態を制御するための新しいビチオフェン同位体添加物を開発した. 3,3-TT添加物は分子パッキングとπ-πスタッキングを大幅に改善し,OSCの効率を20%以上高めました.

キーワード:
ビチオフェン同位体 固体添加物形質の特徴有機太陽電池光伏の特性について選択的な規制

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Acyclic diene metathesis polymerization or ADMET polymerization involves cross-metathesis of terminal dienes, such as 1,8-nonadiene, to give linear unsaturated polymer and ethylene. As ADMET is a reversible process, the formed ethylene gas must be removed from the reaction mixture to complete the polymerization process.
Similar to cross-metathesis, ADMET also involves the formation of metallacyclobutane intermediate by [2+2] cycloaddition of one of the double bonds of a terminal diene with...
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Thermal cycloadditions are reactions where the source of activation energy needed to initiate the reaction is provided in the form of heat. A typical example of a thermally-allowed cycloaddition is the Diels–Alder reaction, which is a [4 + 2] cycloaddition. In contrast, a [2 + 2] cycloaddition is thermally forbidden.
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