圧力下でのフェロセンの構造的安定性およびスペクトル特性に対する電子相関の影響

Alexey A Dyachenko1,2, Alexey V Lukoyanov1,2,3, Vladimir I Anisimov1,2,3

  • 1M. N. Mikheev Institute of Metal Physics of Ural Branch of Russian Academy of Sciences, Yekaterinburg 620108, Russia. dyachenko@imp.uran.ru.

まとめ

高圧下では,フェロセンはポリメリゼーションし,ポリフェロセンは絶縁状態から金属状態に移行する. 構造の変化と相関する鉄イオンの行動によって引き起こされる.

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