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Updated: Sep 9, 2025

Preparation of Contiguous Bisaziridines for Regioselective Ring-Opening Reactions
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Preparation of Contiguous Bisaziridines for Regioselective Ring-Opening Reactions

Published on: July 28, 2022

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アゼチジンの活性化のためのオルガノテルリウムカルコゲン結合触媒の合理的な設計

Fei Jiang1, Lian-Zheng Zuo1, Hao-Wen Zhao1

  • 1Department of Chemistry and Shenzhen Grubbs Institute, Southern University of Science and Technology, Shenzhen, 518055, China.

Angewandte Chemie (International ed. in English)
|September 2, 2025
PubMed
まとめ

この研究は,カルコゲン結合のための新しいビステルロニウム触媒を導入し,アゼチジンの非活性化アルケン/アルキンとのサイクロアディションを初めて可能にします. これらのオルガントルリウム触媒は,ピペリジンとテトラヒドロピリジン構造を効率的に生成します.

キーワード:
アゼチジンビステルロニウムディケーション触媒カルコゲン結合触媒[4+2] サイクル添加

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