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Updated: Sep 9, 2025

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鉄触媒による非対称 [4+2]/ケレトロピックレトロ- [4+1] チオフェンS,S-二酸化物のサイクル添加と3代入インドール

Shi-Xiong Feng1, Qi-Tao Lu1, Yang Lu1

  • 1Department of Chemistry, Fudan University, 220 Handan Rd, Shanghai, 200433, China.

Angewandte Chemie (International ed. in English)
|September 2, 2025
PubMed
まとめ

この研究は,チオフェンS,S-二酸化物とインドルを用いたカルボサイクルの合成のための新しい触媒的非対称的方法を導入している. この新しい鉄触媒反応は,高いエナチオ選択性を持つ貴重な六水素炭酸塩を生成する.

キーワード:
チェレトロピク・レトロ・ [4+1] サイクロアディションドラマチック化インドールアルカロイド逆電子需要ダイエルスアルダー反応チオフェンS,S-二酸化物

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