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Updated: Sep 9, 2025

A Protocol for Safe Lithiation Reactions Using Organolithium Reagents
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カチオンシリルルイス酸の合理的設計

Corinna Girschik1, Saskia Rathjen1, Lina Möllmann1

  • 1Institute of Chemistry, Carl von Ossietzky Universität Oldenburg, Carl von Ossietzky-Str. 9-11, Oldenburg, D-26129, Federal Republic of Germany, European Union.

Chemistry (Weinheim an der Bergstrasse, Germany)
|September 3, 2025
PubMed
まとめ

研究者らはナフタレンまたはアセナフタレン・スキャフォールドを用いて新種のカチオンシリル酸を合成した. これらの化合物は調節可能なルイス酸性を示し,一部はトリス (pentafluorophenyl) ボラン (BCF) の強度を超えています.

キーワード:
ルイス酸度NMR についてセレニウムシリコンシリルカチオン

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