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Updated: Sep 9, 2025

Facile Preparation of 2Z,4E-Dienamides by the Olefination of Electron-deficient Alkenes with Allyl Acetate
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Facile Preparation of 2Z,4E-Dienamides by the Olefination of Electron-deficient Alkenes with Allyl Acetate

Published on: June 21, 2017

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核愛性2アミノアルリルカチオンの先駆体と,電子欠乏アルケンの [3 + 2] サイクル添加におけるその適用のDFT計算支援設計

Chentong Sun1, Chunhao Yuan2, Zongle Shen1

  • 1School of Pharmaceutical Sciences & Institute of Materia Medica, Medical Science and Technology Innovation Center, Shandong First Medical University & Shandong Academy of Medical Sciences, Jinan 250117, Shandong, P. R. China.

Organic letters
|September 4, 2025
PubMed
まとめ

研究者は有機合成のために新しい核愛性2アミノアリルカチオンを開発した. この方法により,エクソサイクル二重結合による最初の非対称 [3+2] サイクル加法が行われ,スピロピロリジンが効率的に生成される.

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