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Updated: Sep 9, 2025

A Microwave-Assisted Direct Heteroarylation of Ketones Using Transition Metal Catalysis
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鉄 ((III) 媒介C−Hアルキル化: 1 電子差異化により活性と化学選択性が増加

Tianyi Zhang1, William G Whitehurst1, Matthew V Pecoraro1

  • 1Department of Chemistry, Princeton University, Princeton, New Jersey 08544, United States.

Journal of the American Chemical Society
|September 4, 2025
PubMed
まとめ

鉄 (III) 複合体は,鉄 (II) 触媒を上回るアレンの選択的C-H機能化を可能にします. これらの新しい有機金属触媒は,C-Hアルキル化反応の反応性を高め,基板の範囲を広げています.

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