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Updated: Sep 9, 2025

A Direct, Regioselective and Atom-Economical Synthesis of 3-Aroyl-N-hydroxy-5-nitroindoles by Cycloaddition of 4-Nitronitrosobenzene with Alkynones
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効率的なアルキルラジカル前駆体としての光化学で活性化された窒素補助オーガノスティビン:機械的洞察と合成応用

Niu Tang1, Xinyu Li1, Chenghan Li1

  • 1State Key Laboratory of Chemo and Biosensing, College of Chemistry and Chemical Engineering, Hunan University, Changsha, Hunan, 410082, P.R. China.

Angewandte Chemie (International ed. in English)
|September 4, 2025
PubMed
まとめ

研究者は,C ((sp3) -SbとC ((sp3) -Bi結合からアルキルラジカルを生成するための新しい有機金属反応剤を開発した. この突破は,光還元触媒による新しいC−C結合形成を可能にし,有機化学における合成の可能性を拡大する.

キーワード:
メイングループ化学オルガノアンチモニーフォトレドックス触媒根本化学についてラジカル前駆体

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