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Updated: Sep 9, 2025

Line Shape Analysis of Dynamic NMR Spectra for Characterizing Coordination Sphere Rearrangements at a Chiral Rhenium Polyhydride Complex
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EPRとP ENDOR 擬似ジョン・テラー力学と機能性窒素酵素モデルにおけるN2活性化の特徴,P3EM (M=Fe,Co;E=Si,B,C)

Hao Yang1, Alex Drena1, George E Cutsail Iii2

  • 1Department of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, Illinois 60208, United States.

Inorganic chemistry
|September 4, 2025
PubMed
まとめ

この研究では,窒素酶モデルにおける擬似ジョン・テラー (PJT) 歪みが窒素 (N2) 活性化にどのように調節されるかを明らかにした. 動的PJT歪みはN2活性化を促進し,静的歪みはそれを阻害し,触媒設計を導く.

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